Single crystal X-ray investigation of norsethite, BaMg(C03h: one more mineral with an aplanar carbonate group

نویسندگان

  • H. Effenberger
  • J. Zemann
چکیده

The crystal structure of norsethite, BaMg(C03h, [a = 5.022(1) Á, e = 16.77(1) Á, space graup Rjm, Z = 3] was reinvestigated by single crystal X-ray methods working with both natural and synthetic material. The main features of an earlier structure determination using powder data were confirmed, but no significant deviation of the atomic arrangement from Rjm was found. The carbonate group is aplanar; the most probable value for the distance of the carbon atom fram the plane defined by the three oxygen atoms is estimated to be 0.044(7) Á.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Empirical correlation for porosity deduction from X-ray computed tomography (CT)

For obtaining reservoir petrophysical properties, for example porosity, non-destructive methods such as X-ray computed tomography, CT, seems to be precise and accurate. Porosity is deducted from the CT image with a single scan via different techniques, such as pore space detection by image segmentation techniques then correlation with porosity. More than one hundred samples with carbonate li...

متن کامل

Redetermination of Crystal Structure of N,N'-bis (2-Hydroxybenzylidene)-2,2-Dimethyl-1,3-Propanediamine

The structure of N,N'-bis(2-hydroxybenzylidene)-2,2-dimethyl-1,3-propanediamine, C19H22N2O2, has been studied at low temperature (120K) by means of single-crystal X-ray diffraction. Solving the structure shows an orthorhombic unit cell, with P212121 space group, Z = 4, a = 6.1046 (4) Å, b = 15.8349 (11)</e...

متن کامل

X-Ray Crystal Structure of [N, N'-bis(4-Methoxysalicylidene) -2, 3-Dimethylaminopropane] Copper(II) Ethanol Solvate

The crystal structure of the title Schiff base complex is obtained by single-crystal X-ray diffraction data.The solid state structure determination reveals that the coordination geometry around the copper(II) center istetrahedrally distorted square-planar. The crystal packing shows one dimensional infinite chains which arisesfrom the intermolecular interaction and stabilize the crystal packing.

متن کامل

SYNTHESIS, X-RAY CRYSTAL STRUCTURE AND IR STUDY OF NEW TRINUCLEAR, BASE CARBOXSYLATE COMPLEX OF [Cu3O(OAc)6(H2O)3]Cl.CH3OH.6H2O

The synthesis of [Cu3O(OAc)6(H2O)3]Cl.CH3OH.6H2O is described. The X-ray crystallographic study of thecomplex revealed an isosceles triangle of copper atoms with a triply bridging oxo atom nearly in the plane of thetriangle. The coordination sphere around each metal center is close to distorted octahedral and the central{Cu3(μ3-O)} core is planar. Every two copper atoms were connected to each o...

متن کامل

Plumbum(II) and Zinc(II) Complexes with 5-Chlorosalicylic Acid: Structure and Propertie

Abstract: Two new transition metal complexes, containing the acidic ligand 5-chlorosalicylic acid (H2L5), and 1,10-phenanthroline(phen) and 1,3-Di(4-pyridyl)propane (bpp) as secondary ligands are reported. They are formulated as {[Pb(HL5)2(phen)(H2O)]·H2O}n(1), [Zn2(HL5)4(bpp)2]n(2). All the complexes are characterized by single-crystal X-ray diffractions. Compoud 1 crystallizes in the triclini...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2006